Boric acid denatured alcohol not mixing

Hey, I’m wondering if when you guys make boric acid and denatured alcohol, does the mixture mixed together or do they stay somewhat separate. Mine is not mixing and staying integrated. The boric acid falls out of solution.

Found this video:

Basically it naturally falls out of solution so I guess this is how it’s supposed to be. All good.

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The chemists among us can tell you why, but the boric acid doesn’t dissolve, it just stays suspended. I keep mine in a tall sealed mason jar and give it a good shake before I use it…Rob

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It dissolves in methyl alcohol but that is toxic and some people avoid using it for that reason. If you don’t get it on your skin and use good ventilation it won’t be that dangerous.

Brennan, boric acid is only slightly soluble in denatured ethyl alcohol, but a little dissolves, and the carry-over of the undissolved powder if you use a brush adds potency. It seems to me that larger lumps stain silver so I avoid that.

Boric acid is more soluble in methyl (wood) alcohol but that has safety concerns like spilling it on skin, breathing the vapors, so most people avoid using that.

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Prips may be a better alternative.

It is not a solution. It is just a suspension of the borax in alcohol. It is never going to be a solution :). Just … shake it up before using :slight_smile:

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No kidding! Prips is easy to make and you probably can find instructions in the archives. The fancy commercial ones don’t seem to work much better. Just MY opinion now … alcohol on the bench scares me to no end. I have enough trouble not burning myself, let alone not setting the studio on fire. A borax cone and water go a long way if you are trying to prevent fire stain. On that matter, lather it up with what ever works for you, use a hot neutral flame and get in and get out. If you heat the damn thing all day nothing is going to help much. Once you start, never pull the flame from the piece, oxygen is your enemy. Have a torch that can provide enough heat. Temperature is not heat. Little butane torches get hot, but can’t put enough BTUs down on a piece of silver of any size, which as you well know just sucks the heat from the join :). Regardless, you still will some degree of fire scale. Buff it out or hide it with depletion guilding (which I think is unethical) you are always going to get some fire stain, it is just a matter of how much. Fire scale is that grayish mess that infilters your silver at high temps, fire scale is that black stuff on the surface which is easily remove by a good pickle. I moved to argentium, which has its own set of issues. Or you could just fire scale the hell out of it and call it handmade :slight_smile:

5 years college chemistry here. Its about 30 years ago now. First to get the boric acid into solution it needs to be in a very hot liquid ie water. But for us we are using denatured alcohol. What happens when you heat the alcohol? it bursts into flame. similar to cooking with alcohol. best just to do as all have suggested, shake the container and you will be fine. Darn now I want some bananas Foster.

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I guess my container is not airtight. I replace the alcohol when needed. Dip or dunk.

My problem is forgetting to close the lid when I am done using it. This represents a potentially serious safety violation as I could easily set the alcohol on fire with a stray motion of my torch. My goal is to try and overcome this habit…Rob

Rio sells a dispenser bottle with a lid:

https://www.riogrande.com/product/pump-dispenser-with-lid-7-oz/504033GP/?code=504033

You press the lid to pump flux into the lid’s top bowl. The description says it can be used with solvents. The pump does get gummed up when the flux dries, but it cleans up with a rinse in warm water.

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I use an artists atomizer to spray Prips, a small squeeze bottle with a larger size hypodermic needle to apply Batterns type flux and an small paintbrush for handi flux or borax and water paste. I use them all along with alcohol and boric acid. My bench has been described by visitors as a chemistry set. I don’t know much about the chemistry but they all seem to have their place…Rob

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Great big smile!

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Be sure your not using borax powder use boric acid it works fine. Shake it up then dip your piece in it. After sitting for a long period it will separate, simply shake and reuse you should not have any clumps. I use it with sunny side brand denatured alcohol And BORIC ACID powder 1 to 1