The Shor salt water refining system is just a simple salt cell. It
has a vessel with a salt solution in it surrounded by more salt
solution. As electric DC current is applied to the anode and the
cathode, chloride ions travel through the vessel walls from the
surrounding solution into it… This creates an excess amount of
chloride ions within it. These ions react with the gold alloy bar
suspended in the vessel and cause the metal to go into solution as
the current passes through it. This creates gold chloride, copper
chloride, nickel chloride, zinc chloride, in a solution (water). The
silver chloride is not very water soluble and will fall to the
bottom of the vessel as a white material.
Out side of the vessel is a solution that is now short of chloride
ions. (hydroxide) Yes this is a very simplified explanation, but for
an answer to the question asked it will do. The short answer is any
solution with chloride ions in it will do. Table salt is sodium
chloride. Sodium chloride will work in this system. Calcium
chloride, ammonium chloride, sodium hypochlorite, and calcium
hypochlorite are others that will work. I think that Shor uses
ammonium chloride, but I am not sure.
The “Odour free Precipitant” is a selective precipitant. This
material will cause the gold in solution to come out of the solution
but leave the other metals in solution to stay dissolved in the
water. The precipitated gold can easily be 995 pure. (but not
necessarily) Possible selective precipitants are, ferrous sulphate
(copperas), sulphur dioxide gas, oxalic acid and sodium nitrite. I
read recently that sodium metabisulfite can also be used. My guess
is that Shor uses sodium nitrite. I must tell you that this refining
system works. I have made several of them over the years. I must
also tell you it is full of hazards and potential pitfalls. Probably
the greatest is the possibility of creating chlorine gas. The
precipitated gold must be carefully cleaned and "fire refining"
would also be advised.
I admit to not knowing what the catalyst is. I do know that it is
not needed for the process to happen. A catalyst just starts and
aids a reaction. I would be interested to know what they use. Having
said all of this I can hardly wait to read what others have to
offer. I love to read the responses here and love the ones from the
chemically wise participants.
Possible other related questions are
testing the solution to know that all of the gold has been
dealing with the platinum group metals
dealing with silver in the alloy
dealing with lead and tin in the alloy
melting the precipitated gold into a button and removing other
impurities as it is melted (fire refining)
disposing of the solutions that are made in an environmentally
the power supply (DC but should it be pulsating)
why not just use a trusted refiner?
Oh what great fun this topic could be.